Heterocycles p. 1067 - 1076 (1990)
Update date:2022-08-04
Topics:
Imakura, Yasuhiro
Okimoto, Kazuto
Gorohata, Chizuru
Kobayashi, Shigeru
Kihara, Masaru
Yamashita, Shinsuke
The reaction of 6-bromopiperonal (1) with sodium alkoxides (MeONa or PhCH2ONa)-alcohols (MeOH or PhCH2OH), and sodium alkoxides (MeONa, PhCH2ONa or PhONa)-phenol (PhOH) in dimethyl sulfoxide gave 3-hydroxybenzene derivatives (3, 5 and 6) and 4-hydroxybenzene derivative (4), respectively.The reactivity and formational mechanism of various nucleophilic reagents (alkoxide anions) formed from the alcohols and phenol by sodium alkoxides in the regioselective cleavage reactions are discussed.
View MoreNaturalin Bio-Resource Co., Ltd
website:http://www.naturalin.com
Contact:+86-0731-84430651
Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
Changsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Shanghai Witshoot Internet Technology Co Ltd
Contact:+86-21-66390020
Address:Room 419, No.285 Luochuan Road (E)
Jiangxi Hessence Chemicals Co., Ltd.
Contact:+86 796 3511924
Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
Wudi Reaction Pharma&Chemical Co.,Ltd.
website:http://www.ruixinchem.com/
Contact:86-543-2257986
Address:Xinhai Industrial Zone, Wudi County,Shandong Province,China.
Doi:10.1016/S0040-4039(00)94721-X
(1990)Doi:10.1016/j.ica.2010.12.024
(2011)Doi:10.1002/ejoc.201100066
(2011)Doi:10.1246/cl.1990.1105
(1990)Doi:10.1021/ja057178b
(2006)Doi:10.1021/ja00002a021
(1991)
