Novel Disilylation and Germylation of Coordinated Dinitrogen in cis-

DOI: 10.1246/cl.1990.1303

Source and publish data:

Chemistry Letters p. 1303 - 1306 (1990)

Update date:2022-09-26

Topics:

Authors:

Oshita, Hiroyuki

Mizobe, Yasushi

Hidai, Masanobu

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Article abstract of DOI:10.1246/cl.1990.1303

When treated with a mixture of ClMe2SiCH2CH2SiMe2Cl and excess NaI, cis- (1) afforded , the structure of which was determined by the X-ray analysis.On the other hand, treatment of 1 with Me3GeCl in the presence of excess NaI gave two germylated dinitrogen complexes trans- and mer-.

Full text of DOI:10.1246/cl.1990.1303

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