The photodissociation of thiophosgene at 248 nm

Article abstract of DOI:10.1063/1.445552

A pulsed molecular beam of thiophosgene was photodissociated at 248 nm.The detection of CSCl and Cl2 fragments formed under collision free conditions is evidence for two decomposition pathways: (a) CSCl2 -> CSCl + Cl (b) CSCl2 -> CS(X¹Σ) + Cl2.An estimate for the quantum yield for (a) is calculated to be 0.8 +/- 0.1.An impulsive spectator model is consistent with the measured translational energy distribution in process (a) for which on average 16 +/- 2 kcal/mol is found as translational energy.The results imply a vibrationally excited CSCl fragment.

Full text of DOI:10.1063/1.445552

The photodissociation of thiophosgene at 248 nm
G. S. Ondrey and R. Bersohn
Citation: The Journal of Chemical Physics 79, 175 (1983); doi: 10.1063/1.445552
View online: http://dx.doi.org/10.1063/1.445552
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/79/1?ver=pdfcov
Published by the AIP Publishing
Articles you may be interested in
Photodissociation of ethylbenzene at 248 nm
J. Chem. Phys. 116, 7779 (2002); 10.1063/1.1475749
Photodissociation of ICl at 235–248 nm
J. Chem. Phys. 99, 3461 (1993); 10.1063/1.466169
Photodissociation dynamics of carbon suboxide at 193 and 248 nm
J. Chem. Phys. 94, 7857 (1991); 10.1063/1.460121
Molecular beam studies of the photodissociation of benzene at 193 and 248 nm
J. Chem. Phys. 92, 4222 (1990); 10.1063/1.457780
Photodissociation of thiophosgene
J. Chem. Phys. 66, 2058 (1977); 10.1063/1.434166
This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.16.124 On: Tue, 25 Nov 2014 03:43:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.16.124 On: Tue, 25 Nov 2014 03:43:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.16.124 On: Tue, 25 Nov 2014 03:43:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.16.124 On: Tue, 25 Nov 2014 03:43:16

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
155.33.16.124 On: Tue, 25 Nov 2014 03:43:16