Journal of Organic Chemistry p. 631 - 637 (1991)
Update date:2022-08-03
Topics:
Mori, Yuji
Kohchi, Yasunori
Suzuki, Makoto
Carmeli, Shmuel
Moore, Richard E.
Patterson, Gregory M. L.
Novel isotactic polymethoxy-1-alkenes 1-4 were isolated from tolytoxin-producing blue-green algae belonging to the family Scytonemataceae.Scytonema mirabile produced 1 and 2, whereas 3 and 4 were isolated from S. burmanicum.The gross structures and relative stereochemistries were determined by mass and NMR spectral analyses.The absolute configurations of 1-4 were established by direct comparison with optically active synthetic samples.
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