Isotactic Polymethoxy-1-alkenes from Blue-Green Algae. Synthesis and Absolute Stereochemistry

DOI: 10.1021/jo00002a027

Source and publish data:

Journal of Organic Chemistry p. 631 - 637 (1991)

Update date:2022-08-03

Topics:

Authors:

Mori, Yuji

Kohchi, Yasunori

Suzuki, Makoto

Carmeli, Shmuel

Moore, Richard E.

Patterson, Gregory M. L.

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Article abstract of DOI:10.1021/jo00002a027

Novel isotactic polymethoxy-1-alkenes 1-4 were isolated from tolytoxin-producing blue-green algae belonging to the family Scytonemataceae.Scytonema mirabile produced 1 and 2, whereas 3 and 4 were isolated from S. burmanicum.The gross structures and relative stereochemistries were determined by mass and NMR spectral analyses.The absolute configurations of 1-4 were established by direct comparison with optically active synthetic samples.

Full text of DOI:10.1021/jo00002a027

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