Isotactic Polymethoxy-1-alkenes from Blue-Green Algae. Synthesis and Absolute Stereochemistry

DOI: 10.1021/jo00002a027

Source and publish data:

Journal of Organic Chemistry p. 631 - 637 (1991)

Update date:2022-08-03

Topics:

Authors:

Mori, Yuji

Kohchi, Yasunori

Suzuki, Makoto

Carmeli, Shmuel

Moore, Richard E.

Patterson, Gregory M. L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00002a027

Novel isotactic polymethoxy-1-alkenes 1-4 were isolated from tolytoxin-producing blue-green algae belonging to the family Scytonemataceae.Scytonema mirabile produced 1 and 2, whereas 3 and 4 were isolated from S. burmanicum.The gross structures and relative stereochemistries were determined by mass and NMR spectral analyses.The absolute configurations of 1-4 were established by direct comparison with optically active synthetic samples.

Full text of DOI:10.1021/jo00002a027

Products guided by the article

Product name:(4S,6S,8S,10S,12R,14R,16R,18R)-4,6,8,10,12,14,16,18-octamethoxy-1-tricosene

Cas No:131487-89-3

R&D Labs maybe for 131487-89-3

Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Shenzhen Sungening Medicine Co., Ltd

Contact:+86-871-65110906

Address:Room702, Building 2, 365 Dianchi Road, Kunming, Yunnan Province, P.R. China
Henan Surface Industry Co Ltd

Contact:86-371-86169316

Address:No.1,Shakou Road,Zhengzhou,China

Relevant to this article

Reaction of Bicyclic Endoperoxides with Carbonyl Compounds. A New Approach to 1,2,4-Trioxanes

Doi:10.1021/ja00359a027
(1983)
A GENERAL SYNTHETIC METHOD FOR 2,6-CYCLODECADIENONE SYSTEM BY INTRAMOLECULAR ALKYLATION OF PROTECTED CYANOHYDRINS

Doi:10.1016/S0040-4039(00)81828-6
(1983)
A new method for the synthesis of 2-cyclopenten-1-one-5-carboxylic ester derivatives via Rh₂(OAc)₄-mediated intramolecular C-H insertion reaction of 4Z-β-vinyl-α-diazo β-ketoesters

Doi:10.1016/j.tet.2005.05.106
(2005)
Synthesis of 25-hydroxyprovitamin D₃ from ergosterol: A mild method for the cleavage of hetero Diels-Alder adducts leading to steroidal 5,7-dienes

Doi:10.1055/s-1999-3547
(1999)
Inhibitors of phenylethanolamine N-methyltransferase devoid of α₂-adrenoceptor affinity

Doi:10.1016/j.bmcl.2005.08.033
(2005)
Selective 4-arylation of pyridines by a nonmetalloorganic process

Doi:10.1021/ol052476z
(2005)

Article Doi