Journal of the Chemical Society. Perkin transactions I p. 1815 - 1818 (1996)
Update date:2022-08-02
Topics:
Bigi, Franca
Sartori, Giovanni
Maggi, Raimondo
Valerio-Papa, Claudia
Marzi, Elena
Lanfranchi, Maurizio
Pellinghelli, Maria Angela
2-Amino-2′-hydroxybenzophenones 3 have been synthesized by acylation of phenols with 2-isocyanatobenzoyl chloride 2 in the presence of aluminium trichloride. The ring-chain tautomerism of the reagent 2 promoted by Lewis acid has been established on the basis of a crystal structure analysis of the 1:1 complex formed by 2 and aluminium trichloride.
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