Journal of Organic Chemistry p. 7235 - 7239 (2011)
Update date:2022-08-02
Topics:
Ahammed, Sabir
Saha, Amit
Ranu, Brindaban C.
Aryl azides undergo clean reduction by copper nanoparticles and ammonium formate in water. The surface hydrogen on copper nanoparticles is considered to be the active reducing species. A variety of functionalized aryl azides and aryl sulfonyl azides are reduced by this procedure to the corresponding amines with excellent chemoselectivity in high yields.
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