ASYMMETRIC ALDOL ADDITION REACTIONS OF A CHIRAL 3-SULFONYL-1,3-OXAZOLIDINE-MASKED LITHIUM 2-FORMYLCYCLOHEXANONE ENOLATE

DOI: 10.1016/S0040-4039(00)97190-9

Source and publish data:

Tetrahedron Letters p. 6859 - 6862 (1990)

Update date:2022-08-02

Topics:

Authors:

Hoppe, Inga

Hoppe, Dieter

Herbst-Irmer, Regine

Egert, Ernst

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Article abstract of DOI:10.1016/S0040-4039(00)97190-9

The title compound, prepared by kinetically controlled deprotonation of a stereohomogeneous 2-(2-oxocyclohexyl)-1,3-oxazolidine, undergoes highly anti-stereoselective aldol addition with alkanals.

Full text of DOI:10.1016/S0040-4039(00)97190-9

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Product name:(2S,6S)-2-((S)-1-Hydroxy-2-methyl-propyl)-6-[(2R,4R)-4-phenyl-3-(toluene-4-sulfonyl)-oxazolidin-2-yl]-cyclohexanone

Cas No:132573-06-9

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