Highly stereoselective preparation of nitro olefins and nitro dienes by the addition-elimination of copper-zinc organometallics to β-alkylthio and β-phenylsulfonyl nitro olefins

DOI: 10.1016/S0040-4039(00)79462-7

Source and publish data:

Tetrahedron Letters p. 441 - 444 (1991)

Update date:2022-09-26

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Authors:

Retherford

Knochel Knochel

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Article abstract of DOI:10.1016/S0040-4039(00)79462-7

The addition-elimination of copper-zinc organometallics RCu(CN)ZnX to (E)-1-nitro-2-phenylsulfonyl ethylene 2a gave highly functionalized pure (E) nitro olefins and stereoselectively (1E, 3E) and (1E, 3Z)-1-nitrodienes in excellent yields. β-Alkylthio nit

Full text of DOI:10.1016/S0040-4039(00)79462-7

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