Palladium-catalyzed hetero-cope rearrangement of alkyl allyl N-aryldithiocarbonimidates

DOI: 10.1055/s-1991-26400

Source and publish data:

Synthesis p. 147 - 149 (1991)

Update date:2022-08-02

Topics:

Authors:

Garin Garin

Melendez

Merchan Merchan

Tejero Tejero

Uriel Uriel

Ayestaran

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Article abstract of DOI:10.1055/s-1991-26400

Palladium-catalyzed [3,3] sigmatropic rearrangement of allyl methyl N-aryldithiocarbonimidates affords methyl N-allyl-N-aryldithiocarbamates. Very high yields of rearranged products can be obtained depending on the substitution pattern of the allyl group.

Full text of DOI:10.1055/s-1991-26400

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