Bulletin of the Chemical Society of Japan p. 699 - 701 (1991)
Update date:2022-08-05
Topics:
Fujihara, Hisashi
Chiu, Jer-Jye
Furukawa, Naomichi
The reaction of bis<2,6-bis(bromomethyl)phenyl>disulfide with thiourea or sodium sulfide showed an unusual reductive cleavage of disulfide linkage with elimination of bromine by neighboring-group participation of the generated thiolate anion.Its reaction gave the structurally intriguing thiols which indicated the facile anodic oxidation.
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