Construction of the Tricyclic Core of the Marine Alkaloid Sarain A

DOI: 10.1021/jo00010a006

Source and publish data:

Journal of Organic Chemistry p. 3210 - 3211 (1991)

Update date:2022-07-30

Topics:

Authors:

Sisko, Joseph

Weinreb, Steven M.

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Article abstract of DOI:10.1021/jo00010a006

The alkaloidal nucleus of sarain A (1) has been synthesized by a short route involving a <3 + 2> azomethine ylide cycloaddition and an allylsilane /N-sulfonyliminium ion cyclization as key steps.

Full text of DOI:10.1021/jo00010a006

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