THE REACTION OF β-(TRIMETHYLSILYL)ALKYL PHENYL SULFONES WITH OXIRANES. A METHOD FOR STEREOCONTROLLED SYNTHESIS OF HOMOALLYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(00)74491-1

Source and publish data:

Tetrahedron Letters p. 1073 - 1076 (1991)

Update date:2022-08-02

Topics:

Authors:

Kabat, Marek M.

Wicha, Jerzy

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Article abstract of DOI:10.1016/S0040-4039(00)74491-1

The reaction of β-trimethylsilylalkyl sulfones (4a-4b) with oxirane derivatives (5a - 5d, 9) followed by treatment of the intermediate adducts with sodium hydride, affords O-trimethylsilyl homoallylic alcohols (7a - 7e, 11), mainly (Z) isomers.

Full text of DOI:10.1016/S0040-4039(00)74491-1

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