
Journal of the Chemical Society. Chemical communications p. 394 - 396 (1991)
Update date:2022-08-02
Topics:
Pearson, Anthony J.
Chang, Kieyoung
Alkylation of enolates from tricarbonyl(6-oxocycloheptadiene)iron occurs with complete stereoselectivity trans to the metal, while reduction of the ketone occurs with stereochemistry dictated by the boat conformation adopted by these molecules.
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