Stereocontrolled Multiple Functionalization of Cycloheptadienoneiron Complexes via Enolate Alkylation

DOI: 10.1039/c39910000394

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 394 - 396 (1991)

Update date:2022-08-02

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Authors:

Pearson, Anthony J.

Chang, Kieyoung

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Article abstract of DOI:10.1039/c39910000394

Alkylation of enolates from tricarbonyl(6-oxocycloheptadiene)iron occurs with complete stereoselectivity trans to the metal, while reduction of the ketone occurs with stereochemistry dictated by the boat conformation adopted by these molecules.

Full text of DOI:10.1039/c39910000394

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