Stereocontrolled Multiple Functionalization of Cycloheptadienoneiron Complexes via Enolate Alkylation

DOI: 10.1039/c39910000394

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 394 - 396 (1991)

Update date:2022-08-02

Topics:

Authors:

Pearson, Anthony J.

Chang, Kieyoung

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000394

Alkylation of enolates from tricarbonyl(6-oxocycloheptadiene)iron occurs with complete stereoselectivity trans to the metal, while reduction of the ketone occurs with stereochemistry dictated by the boat conformation adopted by these molecules.

Full text of DOI:10.1039/c39910000394

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Fe(η4-C7H9(OH))(CO)2(P(OPh)3)

Cas No:133964-97-3

R&D Labs maybe for 133964-97-3

ZHEJIANG CHEMICAL INDUSTRY INSTITUTE TECHNOLOGY CO.,LTD(expird)

Contact:86-575-82730298

Address:shangyu
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
WENZHOU M&C FOREIGN TRADE CO.,LTD.

Contact:+86-577-88862917

Address:No.8 Liming West Road,Wenzhou,zhejiang,China

Relevant to this article

Synthesis and redox properties of π-conjugated 4,5-diazafluorene derivatives incorporating 9-cyanomethylene moiety as an electron acceptor

Doi:10.1016/j.tetlet.2011.08.164
(2011)
Metal-free, acid-catalyzed ortho -directed synthesis of anthranilic acid derivatives using carbodiimides

Doi:10.1021/acs.orglett.5b01160
(2015)
Synthesis of 9,10-dihydrosilaanthracenes with substituents ortho to the silicon and methylene bridges

Doi:10.1016/0022-328X(91)86224-E
(1991)
Pyrylium salt promoted substitution reactions of acetals with various silylated nucleophiles

Doi:10.1016/0040-4039(96)01776-5
(1996)
Reactions of α-phenylethynyl-trans-β-styryl complexes with isonitriles: hemi-labile alkyne coordination

Doi:10.1016/0022-328X(91)80092-X
(1991)
Pd-catalyzed cyclization and carbene migratory insertion: New approach to 3-vinylindoles and 3-vinylbenzofurans

Doi:10.1021/ol402368h
(2013)

Article Doi