Solvent Effects on Manganese(III)-Based Oxidative Free-Radical Cyclizations: Ethanol and Acetic Acid

DOI: 10.1021/jo00019a014

Source and publish data:

Journal of Organic Chemistry p. 5544 - 5553 (1991)

Update date:2022-08-04

Topics:

Authors:

Snider, Barry B.

Merritt, John E.

Dombroski, Mark A.

Buckman, Brad O.

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Article abstract of DOI:10.1021/jo00019a014

Ethanol complements the typical solvent, acetic acid, for Mn(III)-based oxidative free-radical cyclizations.Cyclization of enol ether 1c to give gibberellic acid intermediate 6c is successfull in ethanol, but not in acetic acid.Ethanol acts as a reducing

Full text of DOI:10.1021/jo00019a014

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