Solvent Effects on Manganese(III)-Based Oxidative Free-Radical Cyclizations: Ethanol and Acetic Acid

DOI: 10.1021/jo00019a014

Source and publish data:

Journal of Organic Chemistry p. 5544 - 5553 (1991)

Update date:2022-08-04

Topics:

Authors:

Snider, Barry B.

Merritt, John E.

Dombroski, Mark A.

Buckman, Brad O.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00019a014

Ethanol complements the typical solvent, acetic acid, for Mn(III)-based oxidative free-radical cyclizations.Cyclization of enol ether 1c to give gibberellic acid intermediate 6c is successfull in ethanol, but not in acetic acid.Ethanol acts as a reducing

Full text of DOI:10.1021/jo00019a014

Products guided by the article

Product name:Tetrahydro-6a-methyl-1H-cyclopentafuran-1,6(3H)-dione

Cas No:134906-26-6

R&D Labs maybe for 134906-26-6

Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
SJZ THLD IMP & EXP CO LTD

website:http://www.truewingroup.com

Contact:86-311-66699812

Address:NO.600 ZHONGSHAN EAST ROAD SHIJIAZHUANG
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Jiaozuo Zhongwei Special Products Pharmaceutical Co.,Ltd.

website:http://www.zw-pvp.com

Contact:15302105619

Address:Jiaozuo,Henan,China (Mainland)

Relevant to this article

Amyloid peptides incorporating a core sequence from the amyloid beta peptide and gamma amino acids: Relating bioactivity to self-assembly

Doi:10.1039/c1cc15493a
(2011)
New κ³-PNN′- and κ⁴-PNN′O- polydentate ligands: Synthesis, coordination and structural studies

Doi:10.1016/j.ica.2011.09.045
(2011)
A chiral synthesis of (-)-cannabisativine: An application of the highly diastereo-selective hetero Diels-Alder reaction

Doi:10.1016/S0040-4039(00)74295-X
(1991)
Base promoted synthesis of activated cyclopropanes bearing homologated carbonyl groups via tandem Michael addition-intramolecular enolate trapping

Doi:10.1039/c1ob06487h
(2011)
Reactivity of nitrile oxides toward the 5,6-double bond of uracil derivatives: Synthesis of some 5-aroylpyrimidine nucleoside oximes

Doi:10.1021/jo00030a011
(1992)
2-Arylpropionyl chlorides in kinetic resolution of racemic 3-methyl-2,3-dihydro-4H-[1,4]benzoxazines

Doi:10.1007/s11172-011-0149-0
(2011)

Article Doi