DIVERGENTLY STEREOCONTROLLED REACTION OF AN ALLYLIC SILANE BEARING AN ASYMMETRIC ETHEREAL CARBON TOWARD ALDEHYDES

DOI: 10.1016/S0040-4039(00)79929-1

Source and publish data:

Tetrahedron Letters p. 2383 - 2386 (1991)

Update date:2022-07-30

Topics:

Authors:

Nishigaichi, Yutaka

Takuwa, Akio

Jodai, Akifumi

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Article abstract of DOI:10.1016/S0040-4039(00)79929-1

Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i. e., TiCl4 afforded the syn isomer, whereas BF3*OEt2 afforded the anti isomer predominantly.

Full text of DOI:10.1016/S0040-4039(00)79929-1

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