Tetrahedron Letters p. 2383 - 2386 (1991)
Update date:2022-07-30
Topics:
Nishigaichi, Yutaka
Takuwa, Akio
Jodai, Akifumi
Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i. e., TiCl4 afforded the syn isomer, whereas BF3*OEt2 afforded the anti isomer predominantly.
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