DIVERGENTLY STEREOCONTROLLED REACTION OF AN ALLYLIC SILANE BEARING AN ASYMMETRIC ETHEREAL CARBON TOWARD ALDEHYDES

DOI: 10.1016/S0040-4039(00)79929-1

Source and publish data:

Tetrahedron Letters p. 2383 - 2386 (1991)

Update date:2022-07-30

Topics:

Authors:

Nishigaichi, Yutaka

Takuwa, Akio

Jodai, Akifumi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79929-1

Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i. e., TiCl4 afforded the syn isomer, whereas BF3*OEt2 afforded the anti isomer predominantly.

Full text of DOI:10.1016/S0040-4039(00)79929-1

Products guided by the article

Product name:(1R,4S)-1-(2-Chloro-phenyl)-4-methoxy-3-methylene-pentan-1-ol

Cas No:135086-13-4

R&D Labs maybe for 135086-13-4

Chemieliva Pharmaceutical Co., Ltd.

website:http://www.chemieliva.com

Contact:+86-23-67770219

Address:99 Longhua Road, Yubei District, 401147, Chongqing, China Email: sales@chemieliva.com Tel:0086-23-67770219 Fax: 0086-23-67770220 Attn: Andy Huang
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,

Relevant to this article

Pd-catalyzed olefination of furans and thiophenes with allyl esters

Doi:10.1021/ol203013p
(2012)
The synthesis of oligodeoxynucleotides containing 4-thiothymidine residues

Doi:10.1016/S0040-4039(00)79395-6
(1991)
1,2-phenylene-bridged diporphyrin linked with porphyrin monomer and pyromellitimide as a model for a photosynthetic reaction center: Synthesis and photoinduced charge separation

Doi:10.1021/ja00064a021
(1993)
Fumagalone, a reversible inhibitor of type 2 methionine aminopeptidase and angiogenesis

Doi:10.1021/jm0341103
(2003)
Luminescent rhenium(I)-dipyrrinato complexes

Doi:10.1021/ic201877t
(2012)
Michael Addition of Soft Carbon Nucleophiles to Alkylidene Isoxazol-5-ones: A Divergent Entry to β-Branched Carbonyl Compounds

Doi:10.1021/acs.orglett.5b01004
(2015)

Article Doi