DIVERGENTLY STEREOCONTROLLED REACTION OF AN ALLYLIC SILANE BEARING AN ASYMMETRIC ETHEREAL CARBON TOWARD ALDEHYDES

DOI: 10.1016/S0040-4039(00)79929-1

Source and publish data:

Tetrahedron Letters p. 2383 - 2386 (1991)

Update date:2022-07-30

Topics:

Authors:

Nishigaichi, Yutaka

Takuwa, Akio

Jodai, Akifumi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79929-1

Lewis acid mediated allylation of aldehydes by an allylsilane bearing an asymmetric ethereal functionality proceeded in divergently stereocontrolled manners, i. e., TiCl4 afforded the syn isomer, whereas BF3*OEt2 afforded the anti isomer predominantly.

Full text of DOI:10.1016/S0040-4039(00)79929-1

Products guided by the article

Product name:(1R,4S)-1-(2-Chloro-phenyl)-4-methoxy-3-methylene-pentan-1-ol

Cas No:135086-13-4

R&D Labs maybe for 135086-13-4

Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town

Relevant to this article

Pd-catalyzed olefination of furans and thiophenes with allyl esters

Doi:10.1021/ol203013p
(2012)
The synthesis of oligodeoxynucleotides containing 4-thiothymidine residues

Doi:10.1016/S0040-4039(00)79395-6
(1991)
1,2-phenylene-bridged diporphyrin linked with porphyrin monomer and pyromellitimide as a model for a photosynthetic reaction center: Synthesis and photoinduced charge separation

Doi:10.1021/ja00064a021
(1993)
Fumagalone, a reversible inhibitor of type 2 methionine aminopeptidase and angiogenesis

Doi:10.1021/jm0341103
(2003)
Luminescent rhenium(I)-dipyrrinato complexes

Doi:10.1021/ic201877t
(2012)
Michael Addition of Soft Carbon Nucleophiles to Alkylidene Isoxazol-5-ones: A Divergent Entry to β-Branched Carbonyl Compounds

Doi:10.1021/acs.orglett.5b01004
(2015)

Article Doi