Model studies directed towards microalga polyether toxins. A stereoselective entry into C10 cis and trans fused oxane-oxepane subunits

DOI: 10.1016/S0040-4039(00)79692-4

Source and publish data:

Tetrahedron Letters p. 2245 - 2248 (1991)

Update date:2022-08-04

Topics:

Authors:

Alvarez Alvarez

Zurita Zurita

Martin Martin

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Article abstract of DOI:10.1016/S0040-4039(00)79692-4

A new synthetic process for the construction of cis- and trans-fused oxane-oxepane systems starting from (Z,Z)-cyclodeca-2,7-dien-1-ol is described. The Ti(O(i)Pr)₄-catalysed transannular oxirane ring expansion is invoked to explain the chemose

Full text of DOI:10.1016/S0040-4039(00)79692-4

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