STEREOSPECIFIC REDUCTION OF DIASTEREOMERICALLY PURE MENTHYL PHOSPHINATES: A NEW ROUTE TO OPTICALLY ACTIVE PHOSPHINE OXIDES

DOI: 10.1016/S0040-4039(00)92710-2

Source and publish data:

Tetrahedron Letters p. 3375 - 3376 (1991)

Update date:2022-08-05

Topics:

Authors:

Koide, Yasuhiro

Sakamoto, Atsushi

Imamoto, Tsuneo

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Article abstract of DOI:10.1016/S0040-4039(00)92710-2

Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-tert-butylbiphenylide.Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.

Full text of DOI:10.1016/S0040-4039(00)92710-2

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