Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of 1-Halo-1-alkenes with 9-Alkyl-9-BBN Derivatives. A Direct Synthesis of α,β-Unsaturated Ketones

Article abstract of DOI:10.1246/bcsj.64.1999

The synthesis of α,β-unsaturated ketones by means of the palladium-catalyzed cross-coupling reaction between 9-alkyl-9-borabicyclo<3.3.1>nonanes (9-R-9-BBN) and 1-halo-1-alkenes under carbon monoxide atmosphere is described.