Intramolecular free radical cyclizations using acylsilanes as radicalphiles

DOI: 10.1016/0040-4039(91)80820-V

Source and publish data:

Tetrahedron Letters p. 3515 - 3518 (1991)

Update date:2022-09-26

Topics:

Authors:

Tsai, Yeun-Min

Cherng, Chaur-Donp

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Article abstract of DOI:10.1016/0040-4039(91)80820-V

Carbon radicals add intramolecularly to acylsilanes at the carbonyl carbon followed by radical Brook rearrangement to give silylated cyclopentanols or cyclohexanols in good yields.

Full text of DOI:10.1016/0040-4039(91)80820-V

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