Journal of Organic Chemistry p. 5760 - 5761 (1991)
Update date:2022-08-04
Topics:
Mudryk, Boguslaw
Cohen, Theodore
Whereas 2,2-dialkylated oxetanes are cleaved by lithium 4,4'-di-tert-butylbiphenylide to provide the primary organolithium-tertiary oxyanions, the same reaction in the presence of trialkylaluminums gives exclusively the 3-lithio-3,3-disubstituted propoxides, which are trapped by carbonyl compounds in moderate yields.
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