Reaction of azathiabenzene anion with electrophiles. Formation and X-ray analysis of novel heterocyclic compounds from the reaction with carboxylic ester

DOI: 10.1016/S0040-4039(00)92170-1

Source and publish data:

Tetrahedron Letters p. 4359 - 4362 (1991)

Update date:2022-08-04

Topics:

Authors:

Shimizu Shimizu

Hamada Hamada

Ozawa Ozawa

Kataoka Kataoka

Hori Hori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)92170-1

The anion (2) generated from 9-methyl-10-aza-9-thiaphenanthrene (1) reacted with carboxylic ester to give the spiro compounds (9a), (9b) via Sommelet-Hauser rearrangement, whose structures have been confirmed by an X-ray crystal structure determination of (9a).

Full text of DOI:10.1016/S0040-4039(00)92170-1

Products guided by the article

Product name:6-methoxy-6-phenyl-6,6a-dihydro<1>benzothieno<2,3-c>indole

Cas No:136382-98-4

R&D Labs maybe for 136382-98-4

Hubei Xinghuo Chemical Co., Ltd.,

Contact:13925817279 13907299441

Address:Xinghuo Fine Chemistry Industrial Park, Xiaochang County, Hubei Province, China
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district

Relevant to this article

Palladium catalysed tandem cyclisation-anion capture processes. Part 3. Organoboron anion transfer agents

Doi:10.1016/S0040-4020(97)00754-0
(1997)
New synthesis of multisubstituted cyanocyclopropanes by the intramolecular S_N2 alkylation and 1,3-CC insertion reaction of magnesium carbenoids as the key reactions

Doi:10.1016/j.tet.2012.01.059
(2012)
Synthesis, Spectroscopic and X-Ray Structural Characterization of Ternary Complexes of Copper(II) and 2,5-Dimethoxycinnamic Acid with Phenanthrolines

Doi:10.1039/DT9910002109
(1991)
Naphtho[2,1-b:6,5-b′]difuran: A versatile motif available for solution-processed single-crystal organic field-effect transistors with high hole mobility

Doi:10.1021/ja2120635
(2012)
Fe-catalyzed allylic C-C-bond activation: Vinylcyclopropanes as versatile a1,a3,d5-synthons in traceless allylic substitutions and [3 + 2]-cycloadditions

Doi:10.1021/ja300294a
(2012)
Synthesis of silyloxy dienes by silylene transfer to divinyl ketones: Application to the asymmetric synthesis of substituted cyclohexanes

Doi:10.1021/jo202650k
(2012)

Article Doi