Reaction of azathiabenzene anion with electrophiles. Formation and X-ray analysis of novel heterocyclic compounds from the reaction with carboxylic ester

DOI: 10.1016/S0040-4039(00)92170-1

Source and publish data:

Tetrahedron Letters p. 4359 - 4362 (1991)

Update date:2022-08-04

Topics:

Authors:

Shimizu Shimizu

Hamada Hamada

Ozawa Ozawa

Kataoka Kataoka

Hori Hori

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Article abstract of DOI:10.1016/S0040-4039(00)92170-1

The anion (2) generated from 9-methyl-10-aza-9-thiaphenanthrene (1) reacted with carboxylic ester to give the spiro compounds (9a), (9b) via Sommelet-Hauser rearrangement, whose structures have been confirmed by an X-ray crystal structure determination of (9a).

Full text of DOI:10.1016/S0040-4039(00)92170-1

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