Vicarious nucleophilic substitution of hydrogen in electrophilic alkenes

DOI: 10.1016/S0040-4020(01)80963-7

Source and publish data:

Tetrahedron p. 5001 - 5018 (1991)

Update date:2022-08-03

Topics:

Authors:

Makosza Makosza

Kwast Kwast

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Article abstract of DOI:10.1016/S0040-4020(01)80963-7

Carbanions containing leaving groups react in the presence of base with electrophilic alkenes giving products in which vinylic hydrogen is replaced with the carbanion moiety. They are formed via addition - β-elimination pathway analogous to the vicarious

Full text of DOI:10.1016/S0040-4020(01)80963-7

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