
Tetrahedron Letters p. 6421 - 6424 (1991)
Update date:2022-08-02
Topics:
Echavarren, Antonio M.
De Mendoz, Javier
Prados, Pilar
Zapata, Amparo
The synthesis of (+-)-4-epi-acetomycin has been completed by the steroselective ester enolate (Carroll rearrangement of (E)-2-butenyl 2-methylacetoacetate, followed by ozonolysis and acetylation. The synthesis of (+)- acetomycin and its three diastereomers by a related route is also described.
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Doi:10.1246/cl.1991.1461
(1991)Doi:10.1021/ja3015764
(2012)Doi:10.1021/ma300181g
(2012)Doi:10.1016/j.tetlet.2012.01.049
(2012)Doi:10.1007/BF00907137
()Doi:10.1021/jo00022a010
(1991)