THE STUDIES OF CARBENOID REACTIONS OF α-O-ALLYL- or α-N-ALLYL-α'-DIAZOPROPANONE DERIVATIVES CATALYZED BY VARIOUS METAL IONS

Article abstract of DOI:10.3987/COM-90-5626

Both cupric acetylacetonate and palladium(II) acetate are good catalysts to induce the carbon-carbon double bond addition reaction for α-O-allyl- or α-N-allyl-α'-diazopropanone derivatives.The heteroatom did not play an important role in enhancing the carbon-hydrogen bond insertion for compound (3).