
Tetrahedron p. 6189 - 6196 (1991)
Update date:2022-07-30
Topics:
Curran
Kim
Ziegler
1°-Iodo esters, ketones, and nitriles react smoothly in atom transfer addition reactions with alkylsubstituted (nucleophilic) alkynes, but a 3°-iodoester prefers to add to ester-substituted (electrophilic) alkynes. These atom transfer additions are suited
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