Tetrahedron Letters p. 6649 - 6652 (1991)
Update date:2022-08-04
Topics:
Batey, Robert A.
Motherwell, William B.
Radical ring opening reactions of cyclopropyl ketones mediated by samarium(II) iodide-induced single electron transfer have permitted the elaboration of a tandem rearrangement cyclisation strategy.The resultant samarium enolates may be effectively quenched on oxygen or carbon by electrophiles.Key Words: Samarium(II) Iodide Reduction; Cyclopropylcarbinyl Radical Rearrangement; Cyclopropyl Ketone; Radical Cyclisation; Samarium Enolate.
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