Preparation of Simple N-(Dialkylphosphinoyl)hydroxylamines and Alkyl Migration in the Rearrangement of their O-p-Nitrobenzenesulphonates

DOI: 10.1016/S0040-4039(00)92303-7

Source and publish data:

Tetrahedron Letters p. 4769 - 4770 (1991)

Update date:2022-08-04

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Authors:

Harger, Martin J. P.

Shimmin, P. Andrew

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Article abstract of DOI:10.1016/S0040-4039(00)92303-7

N-Phosphinoylhydroxylamines containing only simple alkyl groups (Me, Et, Prⁱ) can be prepared using Me3SiNHOSiMe3; alkyl groups migrate from P to N when the derived O-p-nitrobenzenesulphonates react with base. Key words: N-Phosphinoylhydroxylam

Full text of DOI:10.1016/S0040-4039(00)92303-7

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Product name:N--O-p-nitrobenzenesulphonylhydroxylamine

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