Unusual Farnesyl Pyrophosphate Synthetase Reaction of an Artificial Substrate with Ni(2+)

DOI: 10.1246/cl.1986.1885

Source and publish data:

Chemistry Letters p. 1885 - 1888 (1986)

Update date:2022-08-04

Topics:

Authors:

Maki, Yuji

Watanabe, Gotaro

Saito, Akio

Koyama, Tanetoshi

Ogura, Kyozo

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Article abstract of DOI:10.1246/cl.1986.1885

Farnesyl Pyrophosphate (FPP) synthetase catalyzed the condensation of geranyl pyrophosphate (GPP) with 4-methyl-4-pentenyl pyrophosphate in the presence of Ni(2+) to give an unexpected product, homofarnesyl pyrophosphate having an exomethylene group, together with Z-homofarnesyl pyrophosphate.

Full text of DOI:10.1246/cl.1986.1885

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