Chemistry Letters p. 1885 - 1888 (1986)
Update date:2022-08-04
Topics:
Maki, Yuji
Watanabe, Gotaro
Saito, Akio
Koyama, Tanetoshi
Ogura, Kyozo
Farnesyl Pyrophosphate (FPP) synthetase catalyzed the condensation of geranyl pyrophosphate (GPP) with 4-methyl-4-pentenyl pyrophosphate in the presence of Ni(2+) to give an unexpected product, homofarnesyl pyrophosphate having an exomethylene group, together with Z-homofarnesyl pyrophosphate.
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