Tetrahedron Letters p. 6089 - 6092 (1991)
Update date:2022-09-26
Topics:
Jung, Michael E.
Clevenger, Gary L.
Treatment of 3-tosyl-D-mannose-4,6-acetonide 9 with sodium borohydride affords an epoxy alcohol 11 which on treatment with base gives 1,5-anhydro-D-allitol-4,6-acetonide 15 by a 6-endo opening of the rearranged epoxy alcohol 13 rather than the product of
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