Journal of Organic Chemistry p. 2379 - 2386 (1992)
Update date:2022-08-05
Topics:
Ramachandran, P. Veeraraghavan
Teodorovic, Aleksandar V.
Rangaishenvi, Milind V.
Brown, Herbert C.
The Midland reagent, Alpine-Borane (2a), is excellent for the asymmetric reduction of many acetylenic ketones but it fails with hindered derivatives.On the other hand, B-chlorodiisopinocampheylborane (DIP-Chloride, 4) reacts with hindered α,β-acetylenic k
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