Site selectivity studies on homonuclear metal dimer complexes: substitution reactions of Re2(CO)9L

DOI: 10.1016/0022-328X(92)83023-B

Source and publish data:

Journal of Organometallic Chemistry p. 51 - 64 (1992)

Update date:2022-08-04

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Authors:

Ingham, Wayne L.

Coville, Neil J.

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Article abstract of DOI:10.1016/0022-328X(92)83023-B

The reaction of Re2(CO)9L (L = ^tBuNC, P(O-o-tol)3, P(CH2C6H5)3, R'CN, R' = Me, Et, Pr, Ph) with L' (L' = ^tBuNC, R'CN) in the presence of PdO or Me3NO yields the 2,3-, 2,6- or 1,6-isomers of Re2(CO)8LL'.The PdO reactions give only the

Full text of DOI:10.1016/0022-328X(92)83023-B

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Product name:Re₂(CO)8(CH₃CN)(C₆H₅CN)

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