Homolytic Substitution on Selenium: Formation of Selenium-containing Heterocycles by Direct Carbon-Selenium Bond Formation

DOI: 10.1039/c39920000057

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 57 - 59 (1992)

Update date:2022-08-04

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Authors:

Schiesser, Carl H.

Sutej, Katarina

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Article abstract of DOI:10.1039/c39920000057

Thiohydroxamic esters derived from 5-(benzylseleno)pentanoic acid, 6-(benzylseleno)hexanoic acid and 7-(benzylseleno)heptanoic acid decompose smoothly upon irradiation, with the loss of carbon dioxide, to give tetrahydroselenophene, selenane and selenopane in good yield.

Full text of DOI:10.1039/c39920000057

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