Kinetic Isotope Effects involving Deuteriated Aniline Nucleophiles

DOI: 10.1039/c39900000335

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 335 - 336 (1990)

Update date:2022-07-29

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Authors:

Lee, Ikchoon

Koh, Han Joong

Lee, Bon-Su

Lee, Hai Whang

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Article abstract of DOI:10.1039/c39900000335

Primary and secondary α-deuterium kinetic isotope effects are observed with deuteriated aniline nucleophiles in the S_N2 reactions of 1-phenylethyl and benzyl benzenesulphonates, providing evidence in support of the four centre transition state mechanism for the former reaction.

Full text of DOI:10.1039/c39900000335

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