Kinetic Isotope Effects involving Deuteriated Aniline Nucleophiles

DOI: 10.1039/c39900000335

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 335 - 336 (1990)

Update date:2022-07-29

Topics:

Authors:

Lee, Ikchoon

Koh, Han Joong

Lee, Bon-Su

Lee, Hai Whang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900000335

Primary and secondary α-deuterium kinetic isotope effects are observed with deuteriated aniline nucleophiles in the S_N2 reactions of 1-phenylethyl and benzyl benzenesulphonates, providing evidence in support of the four centre transition state mechanism for the former reaction.

Full text of DOI:10.1039/c39900000335

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:3-nitroanilinium 4-toluenesulfonate

Cas No:14034-63-0

R&D Labs maybe for 14034-63-0

Jinzhou Jiutai Pharmaceutical Co.,Ltd

Contact:+86-0416-5179890

Address:No.41, Taianli, Taihe District, Jinzhou, Liaoning
Wuhan Konberd Biotech Co., Ltd.

Contact:+86-27-87205925

Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Jinan Jiaquan Chemical Co.,Ltd

Contact:+86-531-62318366

Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.

Contact:+86-21-39971718

Address:859 jiadingchengliu shanghai
Fujian Huitian Biological Pharmacy Co., Ltd.

Contact:0086-598-8300831; 8339920

Address:No.46,Taijiang Road,Sanming City,Fujian,China

Relevant to this article

[3]Rotaxane-based dinuclear palladium catalysts for ring-closure Mizoroki-Heck reaction

Doi:10.1021/ol201357b
(2011)
A modified guanosine phosphoramidite for click functionalization of RNA on the sugar edge

Doi:10.1039/c2cc34015a
(2012)
Reactivity of Carbamoyl Radicals. A New, General, Convenient Free-Radical Synthesis of Isocyanates from Monoamides of Oxalic Acid

Doi:10.1021/jo00122a020
(1995)
Copper(II)-mediated cascade oxidative C-C coupling and aromatization: Synthesis of 3-hydroxyphenanthridinone derivatives

Doi:10.1055/s-0032-1316542
(2012)
Design of ICT-PET fluorescent probes for zinc(II) based on 5-aryl-2,20-bipyridines

Doi:10.1016/j.tetlet.2012.09.027
(2012)
Synthesis, characterizations and single crystal structure of di-nuclear azido-bridged Cd(II) coordination polymer with Schiff base precursor (H₂L_pent^OMe): DFT, fluorescence, solvatochromism and in vitro antimicrobial assay

Doi:10.1016/j.ica.2019.119069
(2019)

Article Doi