Control of Ring-Junction Stereochemistry via Radical Cyclization. A New Construction of trans-Decalins

DOI: 10.1246/cl.1992.395

Source and publish data:

Chemistry Letters p. 395 - 398 (1992)

Update date:2022-08-04

Topics:

Authors:

Kawaguchi, Mami

Satoh, Shoji

Mori, Miwako

Shibasaki, Masakatsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1992.395

A stereoselective synthesis of trans-decalins has been developed by use of regiocontrolled 6-endo-trig-radical cyclization of alkenyl bromides with an exo-methylene group in cyclohexane ring.

Full text of DOI:10.1246/cl.1992.395

Products guided by the article

Product name:Cyclohexanecarboxylic acid, 1-(3-bromo-4-methoxy-4-oxo-2-butenyl)-2-oxo-, ethyl ester, (E)-

Cas No:140709-64-4

R&D Labs maybe for 140709-64-4

Tianjin SPHINX SCIENTIFIC LAB.

Contact:+86-022-66211289

Address:Tianda high-tech Park. No.80,the 4th Avenue
Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Wuxi D-Stone International Co., Ltd.

Contact:+86-510-82740567

Address:21F Hengtong Int'l Centre, 215Zhongshan Road, Wuxi, Jiangsu,China
Sino Rarechem Labs Co.Ltd

Contact:+86-0512-62857507

Address:Boji Science Park, No1688C,Taishan road, Suzhou ,China
Sinopharma Yibin Pharmaceutical Co.,Ltd

Contact:86-831-5109854

Address:Luolong Industry Zone

Relevant to this article

Copper promoted Chan-Lam type O-arylation of oximes with arylboronic acids at room temperature

Doi:org/10.1016/j.tetlet.2012.09.003
(2012)
First synthetic analogues of diphosphoinositol polyphosphates: Interaction with PP-InsP₅ kinase

Doi:10.1039/c2cc36044f
(2012)
Synthesis of 3-Trifluoromethylfurans from β,β-Bis(trifluoromethyl) α,β-Unsaturated Ketones and Tin(II) Chloride

Doi:10.1039/c39920000348
(1992)
Porous organic polymer-derived nanopalladium catalysts for chemoselective synthesis of antitumor benzofuro[2,3-b]pyrazine from 2-Bromophenol and Isonitriles

Doi:10.1021/acs.orglett.9b01230
(2019)
Epimerization of mestranol acetate on alumina

Doi:10.1021/jo00929a045
(1974)
Synthesis and Radical-Induced Ring-Opening Reactions of 2'-Deoxyadenosine-2'-spirocyclopropane and Its Uridine Analogue. Mechanistic Probes for Ribonucleotide Reductases

Doi:10.1021/ja00036a077
(1992)

Article Doi