Acylnitrilium ion initiated heteroannulations in alkaloid synthesis. An efficient, stereocontrolled, total synthesis of the Orchidaceae alkaloid (±)-dendrobine

DOI: 10.1021/ja00037a009

Source and publish data:

Journal of the American Chemical Society p. 4089 - 4095 (1992)

Update date:2022-08-05

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Authors:

Lee, Cheol Hae

Westling, Mark

Livinghouse, Tom

Williams, Andrew C.

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Article abstract of DOI:10.1021/ja00037a009

A concise total synthesis of (±)-dendrobine is described that proceeds in eight steps from 2-methylcyclopent-2-en-1-one. The key transformation in this approach is the silver ion mediated cyclocondensation of the isonitrile 6 with the acyl chloride 5. Thi

Full text of DOI:10.1021/ja00037a009

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