Acylnitrilium ion initiated heteroannulations in alkaloid synthesis. An efficient, stereocontrolled, total synthesis of the Orchidaceae alkaloid (±)-dendrobine

DOI: 10.1021/ja00037a009

Source and publish data:

Journal of the American Chemical Society p. 4089 - 4095 (1992)

Update date:2022-08-05

Topics:

Authors:

Lee, Cheol Hae

Westling, Mark

Livinghouse, Tom

Williams, Andrew C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00037a009

A concise total synthesis of (±)-dendrobine is described that proceeds in eight steps from 2-methylcyclopent-2-en-1-one. The key transformation in this approach is the silver ion mediated cyclocondensation of the isonitrile 6 with the acyl chloride 5. Thi

Full text of DOI:10.1021/ja00037a009

Products guided by the article

Product name:5-carbomethoxy-2,2aα,3,4,4aα,5β,6α,7α,7aα,7bα-decahydro-1,7b-dimethyl-4a-hydroxy-6-(1-methylethyl)-1H-cyclopentindol-7-yl 4-phenylbenzoate

Cas No:140835-51-4

R&D Labs maybe for 140835-51-4

Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Eastar Chemical Corporation

website:http://www.eastarchem.com/

Contact:1-800-898-2436

Address:1215 K Street, STE 1700
Chengdu Aslee Biopharmaceuticals, Inc

Contact:18608018419

Address:Chengdu Aslee Biopharmaceuticals, Inc
Quzhou Ruiyuan chemical Co., Ltd

Contact:+86-570-3039321/3039361/3039308

Address:18# Huayang Road,Quzhou High-tech Industrial Park, Zhejiang China.

Relevant to this article

InCl₃ as a powerful catalyst for the acetylation of carbohydrate alcohols under microwave irradiation

Doi:10.1016/j.carres.2005.03.001
(2005)
Synthesis, spectroscopic characterization and crystal structure of novel NNNN-donor μ-bis(bidentate) tetraaza acyclic Schiff base ligands

Doi:10.1016/j.saa.2012.08.064
(2012)
A highly stereoselective synthesis of axially chiral biaryls. Application to the synthesis of a potential chiral catalyst

Doi:10.1016/S0040-4039(00)91558-2
(1992)
Unusual reactivity of bent acenes: Reactions of [6](1,4)naphthalenophane and [6](1,4)anthracenophane with electrophiles

Doi:10.1021/ja00035a049
(1992)
Doi:10.1016/S0022-1139(00)82555-5
(1977)
Preparation and solid-state structural, electronic, and magnetic properties of the 1,3,5-benzene-bridged tris(1,2,3,5-dithiadiazolyl) [1,3,5-C₆H₃(CN₂S₂)₃]

Doi:10.1021/ja00039a008
(1992)

Article Doi