2,5-cyclohexadien-1-one photochemistry. Reversible type B oxyallyl zwitterion formation from photorearrangements of bicyclo[3.1.0]hex-3-en-2-ones

DOI: 10.1021/ja00039a017

Source and publish data:

Journal of the American Chemical Society p. 5068 - 5073 (1992)

Update date:2022-08-04

Topics:

Authors:

Schultz, Arthur G.

Reilly, John

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Article abstract of DOI:10.1021/ja00039a017

Irradiation of 4-cyano-4-[3′-(2-furyl)propyl]-2,5-cyclohexadien-1-one (9a) gave the type B zwitterion-furan cycloadduct 10. Shorter periods of irradiation of 9a enabled isolation of an intermediate, 6-cyano-6-[3′-(2-furyl)propyl]bicyclo[3.1.0)-hex-3-en-2-

Full text of DOI:10.1021/ja00039a017

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