Organic Letters p. 46 - 49 (2013)
Update date:2022-08-05
Topics:
Neufeldt, Sharon R.
Sanford, Melanie S.
A Pd-catalyzed asymmetric alkene 1,2-dioxygenation reaction is described. The diastereoselectivity of the reaction is controlled by tethering a chiral oxime ether directing group to the alkene substrate. The best selectivities are obtained with 8-substituted menthone-derived oxime ether auxiliaries.
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Doi:10.1039/c2cp43595k
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