Tetrahedron Letters p. 2005 - 2008 (1992)
Update date:2022-07-29
Topics:
Dumas, Franoise
D'Angelo, Jean
Benzylic amines 8 react with ketoenoates 7 yielding, after reduction of the primary adducts, 2,5-dialkylpyrrolidines 9 (trans isomer predominating). This reaction has been applied to the synthesis of trans 2-heptyl-5-ethylpyrrolidine, a component of the venom of fire ant (Solenopsis punctaticeps).
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