Applied Organometallic Chemistry p. 635 - 640 (2014)
Update date:2022-07-29
Topics:
Zhao, Xiaohua
Liu, Xiang
Lu, Ming
Low-melting β-cyclodextrin/N-methylurea (NMU) mixture, an efficient catalytic system for ligand-free Suzuki and Heck couplings in the presence of fresh native β-CD-capped Pd0 nanoparticles, has been successfully reported. This natural and convenient system can be performed in air and could afford the corresponding cross-coupled products in good to excellent isolated yields after a simple workup under every low Pd loading (0.05 mol%). Remarkably, the catalytic system can be recycled and reused without loss of catalytic activity. Copyright
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