Reversible heterolytic Si-H bond activation by an intramolecular frustrated Lewis pair

DOI: 10.5560/ZNB.2012-0181

Source and publish data:

Zeitschrift fur Naturforschung, B: Chemical Sciences p. 987 - 994 (2012)

Update date:2022-07-29

Topics:

Authors:

Nie, Wanli

Klare, Hendrik F. T.

Oestreich, Martin

Froehlich, Roland

Kehr, Gerald

Erker, Gerhard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.5560/ZNB.2012-0181

The intramolecular frustrated P/B Lewis pair Mes₂PCH ₂CH₂B(C₆F₅)₂ (7) reacts readily with phenylsilane by heterolytic cleavage of the Si-H bond to give the zwitterion [Mes₂(PhH View More

Full text of DOI:10.5560/ZNB.2012-0181

Products guided by the article

Product name:C₄₄H₃₈BF₁₀PSi

Cas No:1418149-46-8

R&D Labs maybe for 1418149-46-8

Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Beijing Merson Pharmaceutical Co., Ltd

Contact:0086-10-80484934 0086-10-80484574/

Address:2nd Floor , No. 2 Building , No. 14 Houshayu Duan, Jingmi Road ,Shunyi District , Beijing 101318, P.R.China
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA
Mashilabs(shanghai)Co.,ltd

Contact:+86-21-54391580

Address:Room 502,No.65,Lane 2388 Hongxin Road,Shanghai,China

Relevant to this article

SYNTHESIS AND BIOLOGICAL ACTIVITY OF 1,3-DIMETHYL-6-NITRO-7-CARBOXYALKYLAMINOPYRIDO<2,3-D>PYRIMIDINES

Doi:10.1007/BF00773199
(1992)
A novel semisynthetic flavonoid 7-O-galloyltaxifolin upregulates heme oxygenase-1 in RAW264.7 cells via MAPK/Nrf2 pathway

Doi:10.1021/jm3013344
(2013)
Asymmetric [3+2] cycloaddition of azomethine ylides catalyzed by silver(I) triflate with a chiral bipyrrolidine-derived phosphine ligand

Doi:10.1055/s-0032-1316779
(2012)
Diastereofacial selectivity in uncatalyzed Diels-Alder cycloadditions involving α,β-unsaturated esters and lactones with stereogenic centers containing oxygen functiionalities

Doi:10.1016/S0040-4020(01)88527-6
(1992)
Synthesis and Characterization of Palladium(II) and Platinum(II) Complexes Containing Monodentate Phosphorus Donating or Chelating 2-(Dimethylphosphino)pyridine (PMe2py)

Doi:10.1246/bcsj.63.3434
(1990)
A fluorescent ratiometric chemodosimeter for Cu²⁺ based on TBET and its application in living cells

Doi:10.1021/ol3032889
(2013)

Article Doi