The design, synthesis and validation of recoverable and readily reusable siloxane transfer agents for Pd-catalyzed cross-coupling reactions

DOI: 10.1021/ol400922j

Source and publish data:

Organic Letters p. 2454 - 2457 (2013)

Update date:2022-08-04

Topics:

Authors:

Martinez-Solorio, Dionicio

Hoye, Adam T.

Nguyen, Minh H.

Smith, Amos B.

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Article abstract of DOI:10.1021/ol400922j

The development of competent, recoverable and reusable 1-oxa-2- silacyclopentene (siloxane) transfer agents for Pd-catalyzed cross-coupling reactions (CCRs) of organolithium reagents with aryl and alkenyl iodides has been achieved. Drawbacks of the first-generation siloxane-transfer agent (1), relating to facile recovery for potential recycling, have been addressed.

Full text of DOI:10.1021/ol400922j

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