Generation and Intramolecular Cycloaddition of o-Quinonemethides in Protic Solvent. An Efficient Synthesis of (-)-trans-Hexahydrocannabinol

DOI: 10.1246/cl.1992.1237

Source and publish data:

Chemistry Letters p. 1237 - 1238 (1992)

Update date:2022-09-26

Topics:

Authors:

Lu, Zhan Guo

Sato, Naoki

Inoue, Seiichi

Sato, Kikumasa

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Article abstract of DOI:10.1246/cl.1992.1237

A very facile and efficient synthesis of (-)-trans-hexahydrocannabinol was achieved through the intramolecular Diels-Alder reaction of an o-quinonemethide derived from 2-(1-hydroxycitronellyl)olivetol 1,3-bismethoxymethyl ether in methanol.

Full text of DOI:10.1246/cl.1992.1237

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