Journal of Organic Chemistry p. 7014 - 7017 (1992)
Update date:2022-07-31
Topics: Regioselectivity Yield Catalyst Nucleophile Addition reaction Steric hindrance Protonation Phenols Reaction Mechanism Halogenation Solvent Effects Spectroscopic Analysis Synthetic pathway Electrophilic addition
Feiring, Andrew E.
Wonchoba, Edward R.
Fluorinated ethers ArOCF2CFHOR(f) are obtained in good yield by base-catalyzed addition of phenols to perfluoroalkyl vinyl ethers, CF2=CFOR(f) (R(f) = C3F7, C3F7OCF(CF3)CF2, CH3O2CCF2CF2OCF(CF3)CF2).Reaction of sodium phenoxides with fluorinated vinyl eth
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