Concise Allene Synthesis from Propargylic Alcohols by Hydrostannation and Deoxystannylation: A New Route to Chiral Allenes

DOI: 10.1016/S0040-4039(00)61198-X

Source and publish data:

Tetrahedron Letters p. 5093 - 5096 (1992)

Update date:2022-07-29

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Authors:

Konoike, Toshiro

Araki, Yoshitaka

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Article abstract of DOI:10.1016/S0040-4039(00)61198-X

Propargylic alcohols were converted to allenes in a two-step one-pot process comprised of hydrostannation of propargylic alcohols and subsequent deoxystannylation.Chiral (S)-2,3-decadiene of high enantiomeric excess (ee) can be prepared in a similar way.

Full text of DOI:10.1016/S0040-4039(00)61198-X

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