
Tetrahedron Letters p. 7043 - 7046 (1992)
Update date:2022-08-06
Topics:
Clayden
Collington
Warren
δ-Hydroxy allylic phosphine oxides 5 undergo asymmetric epoxidation to yield epoxy alcohols 6 with high enantio- and diastereoselectivity. Kinetic resolutions are also successful, even with a chiral centre remote from the allylic hydroxyl, if that chiral
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Doi:10.1016/j.tetasy.2013.07.005
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(1987)