Asymmetric epoxidations and kinetic resolutions of δ-hydroxy allylic phosphine oxides

DOI: 10.1016/S0040-4039(00)60928-0

Source and publish data:

Tetrahedron Letters p. 7043 - 7046 (1992)

Update date:2022-08-06

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Authors:

Clayden Clayden

Collington

Warren Warren

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Article abstract of DOI:10.1016/S0040-4039(00)60928-0

δ-Hydroxy allylic phosphine oxides 5 undergo asymmetric epoxidation to yield epoxy alcohols 6 with high enantio- and diastereoselectivity. Kinetic resolutions are also successful, even with a chiral centre remote from the allylic hydroxyl, if that chiral

Full text of DOI:10.1016/S0040-4039(00)60928-0

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