Tetrahedron Letters p. 7087 - 7088 (1992)
Update date:2022-07-31
Topics:
Nikitenko, Antonia A.
Arshava, Boris M.
Mikerin, Igor E.
Raifeld, Yuri E.
Lee, Ving J.
Lang Jr., Stanley A.
The cleavage of the oxirane ring of 3,4-anhydro-2deoxy-D-threo-pentose diethyl acetal by (isopropoxy)-titanium fluorides is discussed. The high regioselectivity found with bis(isopropoxy) titanium difluoride is the basis for an enantioselective synthesis of 3-fluoro-2,3-deoxy-D-erythreo-pentose from a non-carbohydrate precursor.
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