A New Route to Dithiadiazafulvalene Derivatives from Mesoionic Thiazoles. Formation of a Ten-membered Macrocycle by Oxidation with Oxygen and in situ Generation of a Charge Transfer Complex with Tetracyanoquinodimethane

DOI: 10.1039/c39930000601

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 601 - 602 (1993)

Update date:2022-08-05

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Authors:

Bssaibis, Mohammed

Robert, Albert

Lemagueres, Pierre

Ouahab, Lahcene

Carlier, Roger

Tallec, Andre

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Article abstract of DOI:10.1039/c39930000601

Mesoionic thiazoles are starting materials for the preparation of oxygen sensitive dithiadiazafulvalenes, which can be reacted in situ with acceptor derivatives to give the corresponding charge transfer complexes while their reaction with oxygen leads to a ten-membered macrocycle.

Full text of DOI:10.1039/c39930000601

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