Chemical Communications p. 11671 - 11673 (2013)
Update date:2022-08-02
Topics:
Yoshida, Hiroto
Shinke, Ayako
Takaki, Ken
A copper(i)-phosphine complex has been found to facilely promote the distannylation of alkynes with the aid of a base, where a catalytically generated Cu-Sn species serves as a key intermediate. The broad versatility of the copper catalysis has been demonstrated by the facile distannylation of unfunctionalized aliphatic alkynes, being hardly achievable with the conventional palladium catalysts.
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