ISOMERIZATION OF 1-TRIMETHYLSILYLALLENYL ETHER TO 1-TRIMETHYLSILYLPROPARGYL ETHER. PREPARATION OF 1-METHOXY-1-ALKEN-3-YNES and 2-METHOXY-2,5-DIHYDROFURANS

DOI: 10.1016/S0040-4039(00)81604-4

Source and publish data:

Tetrahedron Letters p. 1061 - 1064 (1983)

Update date:2022-09-26

Topics:

Authors:

Kuwajima, Isao

Sugahara, Shuichi

Enda, Jun

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81604-4

On treatment of LDA, methyl 1-trimethylsilylallenyl ether isomerizes to lithium acetylide of 1-trimethylsilylpropargyl ether, which can be used efficiently for the preparation of 1-methoxy-1-alken-3-ynes and 2-methoxy-2,5-dihydrofurans.

Full text of DOI:10.1016/S0040-4039(00)81604-4

Products guided by the article

Product name:Furan, 2-(1-methyl-1-phenylethyl)-

Cas No:15057-16-6

R&D Labs maybe for 15057-16-6

SJZ Chenghui Chemical Co., Ltd.

Contact:86-311-87713916

Address:no.368 youyi north avenue
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Anhui Jiatiansen Agrochemical Co.,Ltd

Contact:15366811918

Address:chemical industrial park,xiangyu town,dongzhi county,anhui,china
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road

Relevant to this article

(S)-N-methyldihydroquinazolinones are the active enantiomers of retro-2 derived compounds against toxins

Doi:10.1021/ml400457j
(2014)
Two novel indolo[3,2-b]carbazole derivatives containing dimesitylboron moieties: Synthesis, photoluminescent and electroluminescent properties

Doi:10.1039/c4nj00140k
(2014)
Theoretical calculations and experimental verification of the antibacterial potential of some monocyclic β-lactams containing two synergetic buried antibacterial pharmacophore sites

Doi:10.1080/10426500903095556
(2010)
Platinacycloalkane complexes containing [P,N] bidentate ligands: Synthesis and decomposition studies

Doi:10.1039/c3dt52798k
(2014)
Design, synthesis, X-ray analysis, and dopamine receptor-modulating activity of mimics of the 'C5' hydrogen-bonded conformation in the peptidomimetic 2-oxo-3(R)-[(2(S)-pyrrolidinylcarbonyl)amino]-1- pyrrolidineacetamide

Doi:10.1021/jm00048a003
(1994)
Role of non-covalent interactions in the supramolecular architectures of mercury(ii) diphenyldithiophosphates: An experimental and theoretical investigation

Doi:10.1039/d0nj05709f
(2021)

Article Doi