
Tetrahedron Letters p. 4593 - 4596 (1980)
Update date:2022-08-05
Topics:
Krow, Grant R.
Szczepanski, Steven
Reaction of camphor with hydroxylamine-O-sulfonic acid affords the nitrogen insertion product α-camphidone by migration of the methylene group rather than the bridgehead. Since Beckmann rearrangements of trigonal oximes afford bridgehead cleavage products with camphor, an alternative synchronous rearrangement of a tetrahedral intermediate is proposed for this Beckmann-like reaction.
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